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8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. REFERENCES J Porath, P Flodin. Nature 183:1657, 1959. JC Moore. J Polym Sci, Part A 2:835, 1964. B Ravindranath. Principles and Practice of Chromatography. Ellis Horwood Ltd, UK, 1989, p 317. PA Bristow. Liquid Chromatography in Practise. UK: Hept, 1976, p 16. AB Littlewood. Gas Chromatography. New York: Academic Press, 1970. C Wu. Column Handbook for Size Exclusion Chromatography. New York: Academic Press, 1999. J Seidl, J Malinsky, K Dusek, W Heitz.
11. REFERENCES FW Billmeyer. Textbook of Polymer Science. 2nd ed. New York: Wiley-Interscience, 1971, p 28. WW Yau, JJ Kirkland, DD Bly. Modern Size Exclusion Chromatography. New York: Wiley-Interscience, 1979, p 27 ff. GS Rushbrooke. Introduction to Statistical Mechanics. Oxford, UK: Oxford University, 1949, p 11. B Vollmert. Polymer Chemistry. Heidelberg, Germany: Springer-Verlag, 1973, p 537 ff. CS Wu, L Senak, EG Malawer. J Liq Chromatogr 12(15):2901– 2918, 1989. EG Malawer, JK DeVasto, SP Frankoski, AJ Montana.
2004 by Marcel Dekker, Inc. Yet when such a capillary is used as an SEC detector, the ﬂow time is constant and the relative viscosity becomes hr ¼ h DP ¼ ho DPo (30) the ratio of the solution to solvent pressure drops. 0 c (31) one can combine Eqs (30) and (31) to give [ h] ¼ ln (DP=DPo ) c (32) provided that c is very small. ) Thus an on-line viscosity detector is capable of providing intrinsic viscosity distribution information directly using time slicing analogous to laser lightscattering detection.