By Baxter G.P.
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Additional resources for A Revision of the Atomic Weight of Tin (1916)(en)(4s)
Pelz K, Weissflog W, Baumeister U, Diele S (2003) Liq Cryst 30:115 16. Amaranatha Reddy R, Tschierske C (2006) J Mat Chem, 16:907 17. Takezoe H, Takanishi Y (2006) Jap J Appl Phys 45:597 18. Miyasato K, Abe S, Takezoe H, Fukuda A, Kuze (1983) Jpn J Appl Phys 22:L661 19. Kresse H, Schmalfuss H, Weissflog W (2002) Proceedings of SPIE 4759:222 20. Kresse H (2003) In: Haase W, Wrobel S (eds) Relaxation Phenomena in Dielectric, Magnetic and Superconducting Materials, Springer-Verlag, Heidelberg, 400–422.
If the field is switched off the fan-shaped texture of the SmA phase reappears. Since the polar current response above the transition temperature SmCPA –SmA is identical with that obtained below this temperature, the switching above this temperature can be related to a field-induced transition from the nonpolar SmA phase to the polar SmCS PF phase. For an electric field of 35 V m−1 an enhancement of the transition temperature by about 2K could be detected . 3 Field-induced Enhancement of the Transition Temperature Crystalline-isotropic The third example of bent-core compounds which show a field-induced transition of a non-polar into a polar phase are long-chained members of the following series 49: Mesophase Behaviour at the Borderline 47 Table 1-21.
112] for branched molecules containing four bent-core units. Increasing the numbers of generation of the dendrimer, however, results in compounds which show only a non-polar phase [109, 113]. For side-group polymers, the phase behaviour depends in addition on the number of bent-core units at the polymer backbone, which influences the flexibility or rigidity of the polymer and therefore the degree of freedom to form a polar packing. If in corresponding polysiloxanes each silicon atom is substituted with a bent-core moiety, a polar phase is missing .